Start by cutting your chicken breasts into bite-sized pieces, about 1" to 1 1/2" in size. Dice the onion and bell pepper into similar-sized chunks to ensure even cooking. Also, chop your fresh pineapple to the same size for a consistent texture throughout the dish.
In a mixing bowl, whisk together 1/2 cup chicken broth, light brown sugar, granulated sugar, white vinegar, lemon juice, low sodium soy sauce, tomato paste, garlic powder, ground ginger, freshly ground black pepper, and Sriracha hot sauce if using. Mix well until the tomato paste is fully incorporated and the sugars start to dissolve.
Place the chicken pieces in the slow cooker. Add the diced onion, bell pepper, and pineapple on top of the chicken. Pour the prepared sauce evenly over the ingredients. Give everything a gentle stir to combine, but don’t worry about mixing too much.
Cover the slow cooker and cook on low for 4 to 6 hours or on high for 2 to 3 hours. The chicken should be cooked through and tender, and the vegetables will be softened but still hold their shape.
About 30 minutes before serving, mix 1/3 cup chicken broth with 1/3 cup cornstarch in a small bowl until smooth. Stir this slurry into the slow cooker, then cover and continue cooking for the final 30 minutes. This step thickens the sauce to a glossy, luscious consistency.
Once thickened, give the dish a final stir and taste to adjust seasoning if needed. Serve your Slow Cooker Sweet and Sour Chicken over steamed white rice or fluffy quinoa for a satisfying meal. Garnish with chopped green onions or sesame seeds for an extra touch.