Line an 8x8 or 9x9 baking dish with parchment paper so the paper overhangs on two opposite sides to create “handles” for easy removal.
In a large bowl, combine 1cup unsalted butter (melted and slightly cooled) and 1 1/2cups creamy peanut butter. Stir or beat until smooth and uniform.
Add 1 1/2cups powdered sugar to the butter–peanut butter mixture and mix until fully incorporated and smooth.
Stir in 2cups graham cracker crumbs until the mixture is evenly combined and holds together when pressed.
Transfer the peanut butter base to the prepared pan. Press the mixture firmly and evenly into the pan using the back of a spatula or the bottom of a measuring cup to create a smooth, compact layer.
In a microwave-safe bowl, combine 1 1/2cups chopped chocolate and 1/4cup creamy peanut butter. Microwave in 20–30 second intervals, stirring between each interval, until the chocolate is melted and the mixture is smooth and glossy. (Alternatively, melt together in a heatproof bowl set over barely simmering water.)
Pour the melted chocolate–peanut butter mixture over the pressed base and spread evenly with a spatula.
Sprinkle 1/4cup roasted peanuts (chopped) evenly over the chocolate layer.
Chill the pan in the refrigerator for at least 2 hours, until the bars are firm. Use the parchment “handles” to lift the slab from the pan, then cut into bars and serve.